The Jesse James remorse tour continues: In an excerpt from tonight's Nightline interview released by ABC, James says he "wanted to get caught" cheating on his wife, Oscar winner Sandra Bullock. It's the first time he's spoken out since separating from Bullock. "When I was doing it, you know, one, I knew it was horrible. It made me feel horrible," James said. He didn't bother justifying his actions, but said he had led a "pretty amazing life and threw it all away," adding that he still loves and cares for Bullock. James also referred to himself as "the most hated man in the world."