Beauty is only skin-deep, even in Hollywood. Angelina Jolie and Brad Pitt, Oprah, and Bono are facing off on Celebs Gone Good, a website where fans vote for stars who’ve made the biggest charitable impact in 2009. Other stars who have made the site’s top 100 givers? Selena Gomez (children’s rights), Faith Hill (cancer, troops/mental health), Hugh Jackman (poverty), Randy Jackson (disadvantaged youth), Neil Patrick Harris (Cancer/LGBT, education), and Reese Witherspoon (Cancer, domestic abuse, youth). The site, which is the offspring of the teen charity “DoSomething,” will feature their top 20 winners on VH1 on Nov 19.